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Citation: Gu Kequan, Zou Xinzhou. OPTICALLY ACTIVE METHOXYTHRIN: SYNTHESIS AND THE STRUCTURE-ACTIVITY RELATION[J]. Chinese Journal of Applied Chemistry, ;1989, 6(4): 22-25. shu

OPTICALLY ACTIVE METHOXYTHRIN: SYNTHESIS AND THE STRUCTURE-ACTIVITY RELATION

Gu Kequan ,
Zou Xinzhou

1.
Department of Chemistry, East China Nomal University, Shanghai

Received Date: 15 October 1988
Available Online: 23 January 1989

The Goffinet's method for resolution of (±)-trans-chrysanthemic acid and the Campbell's method for resolution of (±)-cis-chrysanthemic acid have been improved. The(+)-cis acid and the (-)-cis acid were resolved only by using quinine alone. Four esters were obtained by esterifacation.The results showed: (1)The biological activity of Methoxythrin is in relation of the configuration of chrysanthemic acid and the ester of (-)-(1R,3R)-trans acid showed the highest activity. (2)The biological activity of the compounds varies from insect to insect tested.
- Methoxythrin,
- Optical activity,
- Structure-activity relation,
- Pesticide
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