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Citation: Jin Songchun, Lin Yonghua, Jin Yingtai, Li Xingmin, Sun Yufang. THE CRYSTAL STRUCTURE OF(CF₃OCO)₂NdCl·6EtOH AT LOW TEMPERATURE[J]. Chinese Journal of Applied Chemistry, ;1986, 3(6): 44-47. shu

THE CRYSTAL STRUCTURE OF(CF₃OCO)₂NdCl·6EtOH AT LOW TEMPERATURE

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 31 July 1985
Available Online: 21 March 1986

The crystal of the title compound is triclinic with space group PI and a=11.949(6)Å, b=12.886(5)Å, c=11.557(6)Å, α=112.93(3)°, β=115.92(4)°, γ=82.41(4)°. Diffraction bata of 3739 independent reflections were collected on Nicolet XRD R3 four circle diffractometer using Mokα radiation. The crystal structure was solved by the heavy atom method and difference Fourier synthesis and refined by the block least square to a final R=0.113 based on 3019 unique reflections upon F₀≥3σ(F₀). the structure analysis showed that the coordination of neodymium by oxygen atoms is eightfold with a geometry of a slightly distorted square antiprism and average Nd-O bond length 2.453Å and O-Nd-O angle ranged from 69.3°to 147.4°
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THE CRYSTAL STRUCTURE OF(CF₃OCO)₂NdCl·6EtOH AT LOW TEMPERATURE