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Citation: Zheng Zhongkui, Yang Tianrong, Wang Yujie, Zhao Qingyue. THE MECHANISM OF OXIDATION-DEHYDROAROMATIZATION OF PROPYLENE ON BI-PYSTEM CATALYSTS[J]. Chinese Journal of Applied Chemistry, ;1986, 3(6): 30-35. shu

THE MECHANISM OF OXIDATION-DEHYDROAROMATIZATION OF PROPYLENE ON BI-PYSTEM CATALYSTS

1.
Changchun Institute of Applied Chemistry, Academic Sinica

Received Date: 22 August 1985
Available Online: 13 December 1985

The physicochemical properties of Bi-P catalyst system and the mechanism of oxidation-dehydrodimerization and aromatization of propylene were investigated by using XPS,PAS, TPR and X-ray diffraction methods.The results indicated that propylene is dissociatively adsorbed on the surface of the catalyst and the activation of α-hydrogen is related to the strength of metal-oxygen bond in the catalyst. The products of allyl oxidation depend on the electron transference between the allylic intermediates and the catalyst.
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