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Citation: Chen Yuanyin, Feng Minhua. SYNTHESES AND PROPERTIES OF NETWORK POLYMERIC CROWN ETHERS Ⅰ. FROM BISGLYCIDYL ETHER,ETHYLENE GLYCOL BISGLYCIDYL ETHER OR DI(OR TRI, TETRA) ETHYLENE GLYCOL BISGLYCIDYL ETHER[J]. Chinese Journal of Applied Chemistry, ;1986, 3(5): 28-33. shu

SYNTHESES AND PROPERTIES OF NETWORK POLYMERIC CROWN ETHERS Ⅰ. FROM BISGLYCIDYL ETHER,ETHYLENE GLYCOL BISGLYCIDYL ETHER OR DI(OR TRI, TETRA) ETHYLENE GLYCOL BISGLYCIDYL ETHER

1.
Department of Chemistry, Wuhan University

Received Date: 29 May 1985
Available Online: 20 September 1985

The synthetic method and properties of a series of new network polymeric crown ethers were reported in this paper. Eight network polymeric crown ethers were prepared by the net-polymerization of bisglycidyl ether, ethylene glycol bisglycidyl ether, diethylene glycol bisglycidyl ether triethylene glycol bisglycidyl ether and tetraethylene glycol bisglycidyle ther in the presence of BF₃·OEt₂ or (i-Bu)₃Al as catalyst. The studied network polymeric crown ethers have good cation-complexing ability and effective catalytic activity in the nucleophilic substitution of PhOK with n-BuBr.
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SYNTHESES AND PROPERTIES OF NETWORK POLYMERIC CROWN ETHERS Ⅰ. FROM BISGLYCIDYL ETHER,ETHYLENE GLYCOL BISGLYCIDYL ETHER OR DI(OR TRI, TETRA) ETHYLENE GLYCOL BISGLYCIDYL ETHER

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com