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Citation: Gao Xiaoye, Shi Youlin, Zhang Haoyu, Wang Shiquan, Zhang Zhenyu. STUDY ON THE REACTION OF OXYGEN EVOLUTION ON PbO₂ ELECTRODE BY MEANS OF A. C. IMPEDANOE MEASUREMENT[J]. Chinese Journal of Applied Chemistry, ;1983, 1(1): 87-93. shu

STUDY ON THE REACTION OF OXYGEN EVOLUTION ON PbO₂ ELECTRODE BY MEANS OF A. C. IMPEDANOE MEASUREMENT

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 20 December 1982
Available Online: 6 June 1983

The anodic reaction of oxygen evolution on PbO₂ electrode was studied by A. C. impedance measurement. The Faradaic. resistance R_t,double layer capacitance C_d adsorption resistance R_a and adsorption capacitance C_a were determined by analyzing the impedance spectra with microcomputer curve-fitting method. The rate-controlling step of the reaction was considered to be (OH)_ad+H₂O→(O)_ad+H₃O+e^-1. The relation between C_d, C_a.and OH^-1 ion concentration was discussed in view of the adsorption effect.
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STUDY ON THE REACTION OF OXYGEN EVOLUTION ON PbO2 ELECTRODE BY MEANS OF A. C. IMPEDANOE MEASUREMENT

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通讯作者: 陈斌, bchen63@163.com

STUDY ON THE REACTION OF OXYGEN EVOLUTION ON PbO₂ ELECTRODE BY MEANS OF A. C. IMPEDANOE MEASUREMENT