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Citation: Lin Yonghua, Hu Ninghai, Zhou Qinglian, Wu Shixue. CRYSTAL STRUCTURE OF GADOLINIUM PENTAPHOSPHATE[J]. Chinese Journal of Applied Chemistry, ;1983, 1(1): 33-39. shu

CRYSTAL STRUCTURE OF GADOLINIUM PENTAPHOSPHATE

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 25 April 1983
Available Online: 2 June 1983

The crystal of gadolinium pentaphosphate belongs to the monoclinic system.The space group is P_2₁/a.The crystal parameters are a=12.910(9), b=8.889(10), c=8.721 (6)Å, β=90.53, z=4. The diffraction data have been collected by using PW-1100Four-Circle Diffractometer. The total number of independent diffraction amounts to 2012. The structure has been solved by heavyatom method, and the structure parameters have been refined by means of full matrix and block-diagonal least square method, R=0.103. The result of structure analysis indicated that the coordination number of gadolinium cation is eight,Gd-Gd distance is 5.902Å.
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