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Citation: Lin Yunqing, Li Shengtian, Zhang Hongfang, Sun Shuhai, Hu Zhenya. SYNTHESIS AND CHARACTERIZATION OF POLYBUTADIENE RUBBER WITH LOW VINYL STRUCTURE CONTENT[J]. Chinese Journal of Applied Chemistry, ;1983, 1(1): 22-27. shu

SYNTHESIS AND CHARACTERIZATION OF POLYBUTADIENE RUBBER WITH LOW VINYL STRUCTURE CONTENT

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 12 April 1983
Available Online: 31 May 1983

Cis-1,4-polybutadiene rubber with vinyl content ranging from 7 to 16% in a form of syndiotactic-1,2-polybutadiene blocks was synthesized with cobalt catalyst systems through two-stage polymerization. The polymer obtained has been characterized by their solubility behavior, infrared spectrum, X-ray diffraction patterns, incipient crystallization temperature and half crystallization time.
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