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Citation: Jin Shangde, Guan Jingwen, Shen Qi, Chen Wenqi, Wang Xinping. SYNTHESES AND STRUCTURES OF COPPER(Ⅱ)-PHTHALOCYANINE DERIVATIVES AND THEIR MOLECULAR FILMS[J]. Chinese Journal of Applied Chemistry, ;1992, 9(3): 20-25. shu

SYNTHESES AND STRUCTURES OF COPPER(Ⅱ)-PHTHALOCYANINE DERIVATIVES AND THEIR MOLECULAR FILMS

1.
Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022

Corresponding author: Shen Qi,
Received Date: 7 January 1991
Available Online: 20 May 1991

In this paper, copper(Ⅱ)·tetra-4-(2-methoxyethanoxy-carbonyl) phthalocyanine (A) and copper(Ⅱ)-tetra 4-(2-butoxyethanoxy carbonyl) phthalocyanine (B) were synthesized and characterized by elemental analysis, FT-IR, ¹H NMR and ESR. UV-vis spectra indicate that most of them are dimeric compounds in CHCl₃ solution. X-ray diffraction patterns of the powder samples showed that the stacking arrangments of the molecules are inter-parallel in the tilted way. Presence of organic substituents in phthalocyanine ring somewhat lowers its thermostability. Surface(π)-area(A) isotherms for both compounds in CHCl₃ solution onto subphase(water) at 20℃ showed the existence of the obvious interchange among the "gas", "liquid", "solid" phases and both compounds could form a better monomolecular layer film.
- phthalocyanine-copper(Ⅲ) derivative,
- synthesis,
- thermogravimetry,
- π-A isotherm,
- monomolecular layer film
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