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Citation: Li Yi, Xu Xiaolong, Zhu Limin, Liu Guozhi. SYNTHESIS OF CYCLOPENTADIENYL ALLYL COMPLEXES OF NEODYMIUM[J]. Chinese Journal of Applied Chemistry, ;2016, 4(5): 82-85. shu

SYNTHESIS OF CYCLOPENTADIENYL ALLYL COMPLEXES OF NEODYMIUM

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Corresponding author: Xu Xiaolong,
Received Date: 10 January 1987
Available Online: 6 April 1987

A solution of Cp₂NdCl-LiCl-THF was prepared successfully and conveniently. The solution can be used to synthesize bis(cyclopentadienyl) organolanthanoid derivatives. Cp₂NdC₃H₅ was prepared from Cp₂NdCl-LiCl-THF solution and C₃H₅Li(1:1)at -78℃.CpNd(C₃H₅)2·THF and Li[CpNd(C₃H₅)₃]·2Dioxan were prepared from[Li(THF)₂]₂ (μ-Cl)₄CpNd.THF and C₃H₅Li(1:2 and 1:3 respectively). The new compounds were characterized by elementalanalysis, GC, MS and IR. The spectra of all three compounds show a band characteristic of η³-allyl moieties.
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