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Citation: Hu Naifei, Wang Jinfu, Li Qilong. ON THE ADSORPTIVE-COMPLEX WAVE OF NICKEL(Ⅱ) WITH THIOSEMICARBAZIDE[J]. Chinese Journal of Applied Chemistry, ;1987, 4(4): 77-79. shu

ON THE ADSORPTIVE-COMPLEX WAVE OF NICKEL(Ⅱ) WITH THIOSEMICARBAZIDE

1.
Department of Chemistry, Beijing Normal University

Corresponding author: Hu Naifei,
Received Date: 10 October 1986
Available Online: 14 January 1987
Fund Project:

In the supporting electrolyte containing 0.10M potassium hydrogen phthalate at pH4.0, a sensitive derivative peak of nickel(Ⅱ)-thiosemicarbazide complex was found by using single-sweep oscillopolarography. The peak potential is -0.80V (SCE). The change of the peak height with the concentration of Ni(Ⅱ) appeared linear in the range from 2.0×10^-7 to 8.0×10^-6M. The character of the peak wave has been studied. It is confirmed that the peak wave is a catalytic pre-wave with adsorptive property and the adsorbed species may be Ni(TSC)₂²⁺.
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