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Citation: He Binglin, Teng Kang, Sun Juntan, Li Hong. PREPARATION AND CATALYTIC PROPERTIES OF POLYMER-BOUND TETRARUTHENIUM CLUSTER: DODECACARBONYLTETRAHYDROTETRARUTHENIUM[J]. Chinese Journal of Applied Chemistry, ;1985, 2(4): 31-35. shu

PREPARATION AND CATALYTIC PROPERTIES OF POLYMER-BOUND TETRARUTHENIUM CLUSTER: DODECACARBONYLTETRAHYDROTETRARUTHENIUM

1.
Institute of Polymer Chemistry, Nankai University

Received Date: 12 October 1984
Available Online: 19 March 1985

Synthesized H₄Ru₄(CO)₁₂ and H₄Ru₄(CO)₁₀(PPh₃)₂ in this laboratory were anchored on the modified polymer supports:P-Ph-CH₂PPh₂, SiO₂Ph-CH₂PPh₂, P-Ph-CH₂N(Et)P(NEt₂)₂. They were used as catalysts for the hydrogenation and isomerization of 1-hexene. The effects of the reaction conditions, i.e.variety of solvents, reaction time,crosslinking density of the organic supports,the polymer ligands used and the ligand/metal ratio of the catalysts on the catalytic properties of the cluster were investigated.
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