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Citation: Liu Jingzhi, Guo Xiangfeng, Xiao Yanwen, Liu Guozhi. STUDY ON THE REACTION OF TRIPYRIDYL π-ALLYLIRON CHLORIDE AND CROTONALDEHYDE[J]. Chinese Journal of Applied Chemistry, ;1988, 5(4): 46-49. shu

STUDY ON THE REACTION OF TRIPYRIDYL π-ALLYLIRON CHLORIDE AND CROTONALDEHYDE

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 3 March 1987
Available Online: 10 June 1987
Fund Project:

The self-condensation of crotonaldehyde was studied in the presence of tripyridyl π-allyl iron chloride.The product was confirmed as 6-methyl 1,3-cyclohexadiene-1-carboxaldehyde by Gc-MS, IR and ~1H NMR.It was suggested that the possible mechanism of the reaction might be the initial ligand exchange of crotonaldehyde with tripyridyl π-allyl iron chloride followed by addition and cyclization with another molecule of crotonaldehyde.The selectivity of reaction was increased greatly by orientation effect of ligand in the complex without side reaction.
- Crotoh aldehyde,
- Self-condensation,
- Tripyridyl π-allyl iron chloride complex
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