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Citation: Chen Liban, Lin Xinxin, Chen Haisheng, Lin Jian. ZINC-ALUMINUM BIMETALLIC CATALYSTS FOR THE COPOLYMERIZATION OF CARBON DIOXIDE WITH PROPYLENE OXIDE[J]. Chinese Journal of Applied Chemistry, ;1988, 5(4): 7-11. shu

ZINC-ALUMINUM BIMETALLIC CATALYSTS FOR THE COPOLYMERIZATION OF CARBON DIOXIDE WITH PROPYLENE OXIDE

1.
Guangzhou Institute of Chemistry, Academia Sinica

Received Date: 1 June 1987
Available Online: 28 July 1987
Fund Project:

Bimetallic catalysts were prepared from a zinc salt, triethylaluminum, and an active proton containing compound.The catalysts were studied for the alternating copolymerization of carbon dioxide with propylene oxide giving poly (propylene carbonate). As a cocatalyst, polymer containing carboxyl groups was superior to water.The catalytic activities of the systems depended on the type of zinc salts,the molar ratio of catalyst's components, and the mixing procedure of the components. It is considered that there exists certain cooperative effect from two metals and a possible structure of the active center was proposed.
- Copolymerization of carbon dioxide with propylene oxide,
- Bimetallic catalyst system,
- Carboxyl containing polymer
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