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Citation: Yuan Jingli, Zhao Guoliang, Wang Guilan, Yuan Wanzhong, Wang Yeng. SYNTHESIS OF CERIUM(IV) COMPLEXES WITH 1,1O-PHENANTHROLINE-1-OXIDE[J]. Chinese Journal of Applied Chemistry, ;1988, 5(3): 73-76. shu

SYNTHESIS OF CERIUM(IV) COMPLEXES WITH 1,1O-PHENANTHROLINE-1-OXIDE

1.
Department of Chemistry, Dalian Institute of Technology

Received Date: 15 June 1987
Available Online: 16 November 1987

Two solid complexes of cerium(Ⅳ) salts with 1,10-Phenanthrolinc-1-oxide(o-phcnNO) were preparcd and characterized, having the composition of Ce(po-henNO) (NO₃)₃(OH)·H₂O and Ce(o-PhenNO)₄(NO₃)(ClO₄)₃·H₂O. IR spectra indicate that the characteristic frequencies assignable to stretching vibration of Ce-O(o-phenNO) bond in these complexes appear in the region of 385-390cm^-1 Vci-N(O-phenNO) in the region of 255-260cm^-1, VN→o and ON→o of free ligand shift to lower wave numbers upon complexation, The molar conductance and IR spectra data show that NO₃^- and CIO₄^- are not coordinated in Ce(oPhenNO)₄(NO₃)(CIO₄)₃·H₂O, and all NO₃^- are coordinated in Ce(c-PhenNO)(NO₃)₃ (OH), H₂O, The UV spectrum of Ce(o-PhenNO)₄(NO₃)(CIO₄)₃. H₂O is similar to that of the free ligand. The complexes are less soluble in some organic solvents than the ligand.
- Cerium,
- 1, 10-phenanthroline-l-oxide,
- Complex
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