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Citation: Gao Shixiang, Yang Wenxiang, Xu Xiaobai. STUDY ON THE CHEMICAL REACTIONS OF PHENANTHRENE WITH NO₂ ON PARTICULATES[J]. Chinese Journal of Applied Chemistry, ;1988, 5(3): 32-38. shu

STUDY ON THE CHEMICAL REACTIONS OF PHENANTHRENE WITH NO₂ ON PARTICULATES

1.
Research Center for Eco-Environmental Sciences, Academia Sinica

Received Date: 3 March 1987
Available Online: 4 January 1988

The reactions of phenanthrene coated on silica gel or on fly ash with NO₂ are studied. GC and GC/MS analyses show that the main products on siqca gel in dark arc nitro-phenanthrencs, as a result of a dominate substitution reaction, while under UV irradiation 2,2'-diformyl dibenzene, nitroso-2-formyl dibenzene, etc. are formed due to photodegradation. There is a remarkable difference between the reactions on silica gel and on fly ash in dark. It may be the results of competitive reaction of water molecule and phenanthrene with NO₂ on silica gel. Ames test of the reaction Products shows that the non-mutagenic phenanthrene undergoes transformation with NO₂ into direct mutagenic secondary pollutant which is more harmful to the health of human than phenanthrene itself.
- Phcnanthrene,
- Air pollutant,
- Photochemical reaction,
- NO₂
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STUDY ON THE CHEMICAL REACTIONS OF PHENANTHRENE WITH NO₂ ON PARTICULATES