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Citation: Zhang Lixin, Ye Fuhan, Qiao Guiwen, Li Liguang. FORMATION OF Li_y(PC)_y TiS₂ INTERCALATION COMPOUND AND ITS EFFECT ON UTILIZATION OF Li/TiS₂ SECONDARY CELL[J]. Chinese Journal of Applied Chemistry, ;1988, 5(3): 15-18. shu

FORMATION OF Li_y(PC)_y TiS₂ INTERCALATION COMPOUND AND ITS EFFECT ON UTILIZATION OF Li/TiS₂ SECONDARY CELL

1.
1. Institute of Corrosion and Protection of Metals, Academia Stntca, Shenyang;
2.
2. Institute of Metals Research, Academia Sinica, Shenyang

Received Date: 23 March 1987
Available Online: 19 June 1987

The structure change of TiS_2 during charge-discharge in Li/TiS₂ secondary cell in 1M LiClO₄-PC (propylenc carbonate) electrolyte was investegated by X-ray diffraction, high resolution electronmicroscopy, thermogravimetry and mass spectroscopy. Two intercalation processes were found: the one is reversible to Li, forming a compound of Li_x TiS₂, the other is irreversible to both Li and PC, forming compounds of Li_y(PC)_y TiS₂, which are the main cause leading to the decrease of the efficiencY of Li/TiS₂ cell after chargedischarge cycles.
- Lithium/Titanium sulfide secondary cell,
- Intercalation compound
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FORMATION OF Liy(PC)y TiS2 INTERCALATION COMPOUND AND ITS EFFECT ON UTILIZATION OF Li/TiS2 SECONDARY CELL

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通讯作者: 陈斌, bchen63@163.com

FORMATION OF Li_y(PC)_y TiS₂ INTERCALATION COMPOUND AND ITS EFFECT ON UTILIZATION OF Li/TiS₂ SECONDARY CELL