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Citation: Tan Shuying, Wang Yuting, Peng Changhong, Tang Yurong, Luan Zhaokun. Adsorption property of Schiff-base Type and Secondary Amine Type Chitosan-Crownethers[J]. Chinese Journal of Applied Chemistry, ;1999, 16(1): 98-100. shu

Adsorption property of Schiff-base Type and Secondary Amine Type Chitosan-Crownethers

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a Department of Environmental Science, Wuhan University, Wuhan 430072;
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b Center of Analysis and Measurement, Wuhan University, Wuhan;
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c Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing

Received Date: 30 June 1998
Available Online: 9 November 1998
Fund Project: 国家自然科学基金(29577281) (29577281)

Two N-Schiff base type chitosan-crownethers (S15-CTS and S18-CTS) were synthesized by reaction of 4'-formylbenzo-15-crown-5 and 4'-formylbenzo-18-crown-6 with chitosan respectively. N-secondary amine type chitosan-crownethers (Z15-CTS and Z18-CTS) were also prepared by reaction of N-Schiff base type chitosan-crow nethers with sodium borohydride.Their static adsorption properties for metal ions (Pd²⁺, Cu²⁺ and Hg²⁺) had been studied. The results showed that four chitosan-crow nethers had good adsorption character and adsorption selectivity for Pd²⁺ in the presence of Cu²⁺ or Hg²⁺.
- N-Schiff base type chitosan-crow nether,
- N-secondary amine type chitosancrow nether,
- metal ion,
- adsorption behavior
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