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Citation: Yan Wei, Song Yilin, Tao Fenggang. Asymmetric Reduction of Prochiral Ketones Catalyzed By Borane-Amino Hydroxycedrane Complex[J]. Chinese Journal of Applied Chemistry, ;1999, 16(4): 74-76. shu

Asymmetric Reduction of Prochiral Ketones Catalyzed By Borane-Amino Hydroxycedrane Complex

1.
Department of Chemistry, Fudan University, Shanghai 200433

Received Date: 8 December 1998
Available Online: 27 April 1999
Fund Project: 国家自然科学基金资助项目(29672006) (29672006)

A novel chiral amino alcohol ligand, (1R,2R,5S,7R,8R,9S)-9-amino-8-hydroxycedrane was synthesized from cedranediol and reacted with borane to form the corresponding complex, oxazaborolidine, that was used as catalyst in the asymmetric reduction of prochiral ketones. Medium stereoselectivities were obtained.
- prochiral ketone,
- asymmetric reduction,
- amino hydroxycedrane,
- borane
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