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Citation: Yu Jianxin, Liu Fangming, Li Yanping, Cheng Liang, Fan Xin, Liu Yuting. Synthesis of 1-Aroyl-4-[1'-N-β-D-glycopyranosyl]-thiosemicarbazides[J]. Chinese Journal of Applied Chemistry, ;1999, 16(4): 41-46. shu

Synthesis of 1-Aroyl-4-[1'-N-β-D-glycopyranosyl]-thiosemicarbazides

1.
Department of Chemistry, Xinjiang University, Urumqi 830046

Received Date: 29 December 1998
Available Online: 25 May 1999
Fund Project: 国家自然科学基金(29862005) (29862005)

The 1-aroyl-4-[1'-N-2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl] thiosemicarbazides (6) and seven 1-aroyl-4-[1'-N-2',3',4'-tri-O-acetyl-β-D-xylopyranosyl] thiosemicarbazides(7) were synthesized by condensation of 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl isothiocyanate (3) and 2,3,4-tri-O-acetyl-β-D-xylopyranosyl isothiocyanate(4) with aroyl hydrazines(5) in 95% EtOH under reflux, respectively, and also 1-aroyl-4-[1'-N-β-D-glucopyranosyl and corre sponding 1'-N-β-D-xylopyranosyl] thiosemicarbazides(8,9) after deacetylation. The structures of the compounds were confirmed by elemental and spectral analyses.
- glycosyl isothiosyanate,
- acylthiosemicarbazide,
- synthesis
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