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Citation: Yan Yan, Tong Shanling, Guo Kui, Zheng Guodong, Zhen Kaiji, Fang Chiguang, Chang Xin. Catalytic Oxidation of Naphthol over Metalloporphyrins Ⅰ.Synthesis of 2-Hydroxy-1,4-naphthaqinone[J]. Chinese Journal of Applied Chemistry, ;1999, 16(4): 28-32. shu

Catalytic Oxidation of Naphthol over Metalloporphyrins Ⅰ.Synthesis of 2-Hydroxy-1,4-naphthaqinone

1.
a Department of Chemistry, Jilin University, Changchun 130021;
2.
b Changchun College of Light Industry, Changchun;
3.
c Department of Light and Textile Industry, Jilin Institute of Technology, Changchun;
4.
d Jilin Provincial Health and Anti-epidemic Station, Changchun

Received Date: 7 January 1999
Available Online: 14 April 1999
Fund Project:

Title compound(HNQ) has been catalytically synthesized from 1- and 2-naphthol over metalloporphyrins in methanol solution of NaOH using hydroperoxide as an oxidant with maximum yield of 40% and 57%, respectively. The method is characteristic of low reaction temperature, high conversion of naphthol, strong alkali medium, easy operation and high yield of the products.
- hydroxy-naphthaqinone,
- preparation,
- nathphol,
- metalloporphyrin,
- catalytic oxidation
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