Citation:
Qiu Guangming. Synthesis of Nanosize Magnetic Microspheres from Fe3O4 and Poly(styrene-acrolein)[J]. Chinese Journal of Applied Chemistry,
;1999, 16(6): 46-49.
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The reactive magnetic microspheres with magnetic core and aldehyde groups on surface were prepared by copolymerization of styrene(St) and acrolein(Ac) in an alcohol/water dispersion medium in the presence of magnetite(Fe3O4) particles wrapped up in polyethylene glycol.The composite microspheres have diameters of 1-5μm, with surface aldehyde groups of 0.9-1.52 mmol/g and Fe3O4 content of 0.9-10.0 mg/g.They showed better magnetic responsibility and excellent monodispersity.The effects of the content of magnetite particle, comonomer, initiator and V(EtOH)/V(H2O) ratio, molar ratio of Ac to St on the preparation have been investigated.
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