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Citation: Zhang Yin, Gao Yang, Huanq Jinqqin, Chen Wenqi. Preparation of Tb(Ⅲ)/Eu(Ⅲ)-Bisphthalocyanine Complexes and the Fluorescence Bahavior of the LB Films Thereof[J]. Chinese Journal of Applied Chemistry, ;1999, 16(6): 33-36. shu

Preparation of Tb(Ⅲ)/Eu(Ⅲ)-Bisphthalocyanine Complexes and the Fluorescence Bahavior of the LB Films Thereof

1.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 6 May 1999
Available Online: 19 July 1999
Fund Project: 吉林省科委青年基金资助课题(970508) (970508)

Four complexes: Tb(Ⅲ)-octa-4-n-nonyloxyphthalocyanine (A),Eu(Ⅲ)-ocat-4-tetrehydrofurfuroxyphthalocyanine(B),Tb(Ⅲ)isphthalocyanine(C),Tb(Ⅲ)-ocia-4-nitrophthalocyanine(D) were synthesized and characterized by elemental analysis, IR, MS and UV-Vis spectra.The π-A isotherm data of B Indicates its good film-forming ability.The LB films of B formed on quarz by Y-type technique have good lumlnescence property, which is better with the thickness of the film. The films doped with o-phenanthroline(phen) show a great relative fluorescence in-tensity than purel,B films.Complex B with phen in molar ratio of 1：10 has best fluores-cence behavior.
- rate earth bisphthlocyanine complex,
- LB film,
- synthesis,
- fluorescence
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