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Citation: ZHAO Yong, HE Bing-Lin, HA Run-Hua. Effect of Emulsifiers on the Copolymerization of Acrylamide in Inverse Microemulsion[J]. Chinese Journal of Applied Chemistry, ;2000, 17(2): 168-170. shu

Effect of Emulsifiers on the Copolymerization of Acrylamide in Inverse Microemulsion

1.
a State Key Laboratory of Functional Polymeric Materials for Adsorption and Separation, Institute of Polymer Chemistry, Nankai University, Tianjin 300071;
2.
b School of Chemical Engineering, Tianjin University, Tianjin

Received Date: 17 September 1999
Available Online: 9 January 2000
Fund Project: 国家自然科学基金资助项目(29474166) (29474166)

Inverse microemulsion copolymerizations of acrylamide(AM) with acrylimide ethyltrimethylammonium chloride(AETMAC) have been carried out in the systems of nonionic emulsifier SPAN-80 and anionic emulsifier sodium di(2-ethyl)-hexyl phosphate(DOP), respectively, and the effects of the emulsifiers on the copolymerization rate and reactivity ratio have been investigated. The copolymerization rate was found higher in DOP system and the reactivity ratio of AETMAC was lower in SPAN-80 system than in DOP system and aqueous solution. The results are explained in terms of the difference in tightness of emulsifier layers.
- acrylamide,
- acrylimide ethyltrimethylammonium chloride,
- inverse microemulsion,
- copolymerization
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