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Citation: LIU Shi-Jun, ZENG Fan-Di, WANG Hai-Qiao. Synthesis and Characterization of Poly(2,5-dioctyloxy-1,4-phenylene)[J]. Chinese Journal of Applied Chemistry, ;2000, 17(5): 512-515. shu

Synthesis and Characterization of Poly(2,5-dioctyloxy-1,4-phenylene)

1.
Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074

Received Date: 28 December 1999
Available Online: 24 March 2000

A blue electroluminescent polymer dioctyloxyl substituted polyparaphenylene(DOO-PPP) was synthesized in nitrobenzene via a chemical oxidative route using FeCl₃ as catalyst. The effects of FeCl₃ amount, temperature, reaction time and monomer concentration on the yield and moleclar weight of DOO-PPP were investigated. The polymer exhibited analogical thermogravimetric behavior both in air and N₂, the peak wavelength of its photoluminescence spectrum in CHCl₃ was at 426 nm.
- poly(dioctyloxy-phenylene),
- blue electroluminescence,
- synthesis,
- characterization
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