Citation:
YANG Shu-Ting, ZHANG Yan-Feng, LÜ Qing-Zhang, JIA Jun-Hua, DING Li, ZHANG Ming-Chun. Electrochemical Behavior of Doped LiMxMn2O4(M=La,Nd,Y) Synthesized Under Microwave Action[J]. Chinese Journal of Applied Chemistry,
;2000, 17(5): 503-506.
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The doped LiMxMn2O4(M=La,Nd,Y) was synthesized from gel precursor on heating in microwave oven. The precursor was obtained from Li2CO3 and Mn(NO3)2 in mixture of citric acid and ethandiol. XRD data indicated the higher phase purity of the sample as compared with that obtained in muffle heating. Charge and discharge experiments revealed that doped LiM0.006 Mn2O4 have better electrochemical behavior than those undoped ones and obtained from muffle heating. Doping of La, Nd and Y increased the specific discharge capacity and charge/discharge performance of the cells.
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Keywords:
- LiMn2O4,
- doping,
- rare earth element,
- microwave heating
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