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Citation: NIU Jing-Yang, WANG Jing-Ping, BO Yan, DANG Dong-Bin, YU Li. Synthesis, Characterization and Nonlinear Property of Charge-Transfer Salts from H₃PMo_xW_12-xO₄₀·nH₂O and N-Methylpyrrolidone[J]. Chinese Journal of Applied Chemistry, ;2000, 17(6): 589-592. shu

Synthesis, Characterization and Nonlinear Property of Charge-Transfer Salts from H₃PMo_xW_12-xO₄₀·nH₂O and N-Methylpyrrolidone

1.
School of Chemistry and Chemical Engineering, He'nan University, Kaifeng 475001

Received Date: 23 February 2000
Available Online: 24 May 2000
Fund Project: 国家自然科学基金(29601002) (29601002)

Six charge-transfer salts,[NMPH]₃PMo_xW_12-xO₄₀·CH₃CN(x=0,1,3,9,11,12) were synthesized from H₃PMo_xW_12-xO₄₀·nH₂O and N-methylpyrrolidone and characterized by elemental analysis and IR spectra. The results suggest that there is a strong interaction between anions and organic cations in solid compounds. The charge-transfer in the compounds will take place under irradiation of light and result in oxidation of organic molecules and reduction of anions. The ESR results indicate the one electron step reduction of anions. The second-order and third-order nonlinear optical property measurements indicate that the SHG and the susceptibilities of the charge-transfer salts increase with the increase of tungsten content in molecule.
- heteropoly acid,
- N-methylpyrrolidone,
- nonli near optical property
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Synthesis, Characterization and Nonlinear Property of Charge-Transfer Salts from H3PMoxW12-xO40·nH2O and N-Methylpyrrolidone

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Characterization and Nonlinear Property of Charge-Transfer Salts from H₃PMo_xW_12-xO₄₀·nH₂O and N-Methylpyrrolidone