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Citation: LIU Feng-Yi, FU Lian-She, LIN Jun, ZHANG Hong-Jie, WANG Shu-Bin, XU Qing-Hong, DING Hong, ZOU Yong-Chun. Synthesis and Characterization of a Novel Hybrid Inorganic-Organic Mesoporous Luminescent Material (phen)₂Eu/MCM-41[J]. Chinese Journal of Applied Chemistry, ;2001, 18(5): 380-383. shu

Synthesis and Characterization of a Novel Hybrid Inorganic-Organic Mesoporous Luminescent Material (phen)₂Eu/MCM-41

1.
a Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022;
2.
b Laboratory of Inorganic Synthesis and Preparative Chemistry,Department of Chemistry, Jilin University, Changchun

Received Date: 29 December 2000
Available Online: 5 April 2001
Fund Project: "九七三"稀土功能材料基础研究(G1998061310) (G1998061310)国家自然科学基金(2973101029971030) (2973101029971030)国家杰出青年基金(29225102)项目资助 (29225102)

A novel hybrid inorganic-organic mesoporous luminescent material (phen)₂Eu/MCM-41 has been synthesized and characterized by XRD, IR, fluorescence and diffuse reflection spectra. In comparison with MCM-41, the hybrid mesoporous material has typical structure of MCM-41 and retains the same pore structure as MCM-41 after the assembly process. The hybrid mesoporous material shows characteristic emission spectra of Eu³⁺ under UV irradiation, but the excitation spectrum has shifted to blue region compared to that of pure rare earth complex. The decrease of site symmetry of Eu³⁺ has been found. The fluorescence lifetime of (phen)₂Eu/MCM-41 is longer than that of pure rare earth complex. The spectra of hybrid mesoporous material have been discussed.
- inorganic-organic hybrid,
- MCM-41,
- luminescent material
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Synthesis and Characterization of a Novel Hybrid Inorganic-Organic Mesoporous Luminescent Material (phen)₂Eu/MCM-41