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Citation: ZHANG Suo-Bo, CHUI Dong-Mei, CHENG Jian-Hua, JIN Ji-Zhu, HU Ning-Hai, CHEN Wen-Qi, LIU Ju-Zheng. Synthesis and Crystal Structure of (2,4-C₇H₁₁)₃Ln(Ln=Dy,Er)[J]. Chinese Journal of Applied Chemistry, ;2001, 18(5): 330-335. shu

Synthesis and Crystal Structure of (2,4-C₇H₁₁)₃Ln(Ln=Dy,Er)

1.
a Changchun Institute of Applied Chemistry, Chinese Academy of Sicences, Changchun 130022;
2.
b Department of Chemistry, Jilin University, Changchun

Received Date: 2 March 2001
Available Online: 2 April 2001
Fund Project: Finaucial support from the special fuuds for Major State Basic Research projects (project No.G1999064801) (project No.G1999064801)

The reaction of LnCl₃ with two equivalents of 2,4-dimethyl-pentadienyl potassium affords (2,4-C₇H₁₁)₃Ln(Ln=Dy,Er). The compound (2,4-C₇H₁₁)₃Dy(1), crystallized from a mixed solvent of hexane and THF has a triclinic space group Pl with a=1.270 2(2) nm, b=1.290 8(2) nm, c=0.847 9(2) nm, T=91.48(2)°, U=108.41(2)°, V=118.41(2)°, Z=2. The compound (2,4-C₇H₁₁)₃Er(2) was crystallized from toluene in triclinic P1 with a=0.909 5(3) nm,b=1.407 2(3) nm, c=1.657 7(6) nm, T=106.66(2)°, U=93.77(3)°, V=89.76(2)°, Z=4. Both structures were solved by using direct methods and refined by block-matrix least-squares to final values of R=0.039 for 1 and R=0.067 for 2. A comparison of some significant structural parameters in (2,4-C₇H₁₁)₃Ln(Ln=Dy,Er) with those from other analogues (2,4-C₇H₁₁)₃Ln(Ln=Nd,Gd) was made.
- dimethylpentadiene,
- rare earth,
- synthesis,
- crystal structure
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Synthesis and Crystal Structure of (2,4-C₇H₁₁)₃Ln(Ln=Dy,Er)