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Citation: TANG Yu, GAN Xin-Min, FENG Yin-Chang, TAN Min-Yu. Synthesis, Characterization and Properties of Zinc Tetrathiafulvalene Tetrathiolate Coordination Polymers[J]. Chinese Journal of Applied Chemistry, ;2001, 18(8): 610-613. shu

Synthesis, Characterization and Properties of Zinc Tetrathiafulvalene Tetrathiolate Coordination Polymers

1.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000

Received Date: 26 November 2000
Available Online: 27 February 2001
Fund Project: 国家自然科学基金资助课题(29671015) (29671015)

Two series of polymers based on zinc complexes of the tetrathiafulvalene tetrathiolate(ttftt^4-) of stoichiometry[(Zn-ttftt)M_x]_n (M=Mn,Co,Ni,Cu,Hg; x=0.3,0.4,0.5,1.3,0.7) and[(Zn ttftt)Ln_y]_n (Ln=La,Er, y=0.5; Ln=Nd,Eu, y=0.6) were prepared in absolute ethanol. The insoluble amorphous polymeric complexes have been characterized by IR spectra and X-ray photoelectron spectrometry and elemental and thermal analysis and conductivity measurements. The complexes behave as semiconductors at 25℃ as compacted pellets. Among them, the compound[(Zn-ttftt)Ni_0.5 ·1.9EtOH]_n showed the highest conductivity of 3.6 S/cm.
- transition metal,
- zinc,
- tetrathiafulvalene tetrathiolate(ttftt^4-),
- coordination polymer
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