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Citation: YAN Cui-Wei, LI Yan-Tuan, LIAO Dai-Zheng. Synthesis,Magnetism and Antibacterial Activity of μ-Oxamido Hetero-binuclear Copper(Ⅱ)-Iron(Ⅱ) and Copper(Ⅱ)-Zinc(Ⅱ) Complexes[J]. Chinese Journal of Applied Chemistry, ;2001, 18(10): 806-809. shu

Synthesis,Magnetism and Antibacterial Activity of μ-Oxamido Hetero-binuclear Copper(Ⅱ)-Iron(Ⅱ) and Copper(Ⅱ)-Zinc(Ⅱ) Complexes

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a Department of Biology, Qufu Normal University, Qufu 27316;
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b Department of Chemistry, Qufu Normal University, Qufu 273165;
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c Department of Chemistry, Nankai University, Tianjin

Received Date: 28 February 2001
Available Online: 10 April 2001
Fund Project: 山东省自然科学基金资助项目(Q99B12) (Q99B12)

Three new _-oxamido heterobinuclear complexes bridged by N,N'-bis(3-amino-2,2-dimethylpropyl)oxamido dianion (Me₂oxpn) and end capped with N,N,N',N' tetramethylethylene diamine (tmen) and 2,9-dimethyl-1,10-phenanthroline (Me₂-phen), respectively; namely,[Cu-(Me₂oxpn)Fe(tmen)₂]SO ₄(a),[Cu(Me₂oxpn)Zn(tmen)₂]SO₄(b) and[Cu(Me₂oxpn)Zn(Me₂-phen)₂]SO₄(c), have been synthesized and characterized by elemental analyses, magnetic moment and molar conductivity measurements, and spectrometry. These complexes appeared to have oxamido bridged structures consisting of planar copper(Ⅱ) and octahedral iron(Ⅱ) ions. The temperature dependence of magnetic susceptibilities of the complex (a) has been measured at 4~300 K, giving the exchange integral J=-12.96 cm^-1. The results indicated the existence of antiferromagnetic superexchange interactions between the metal ions. The antibacterial activity of the complexes was also examined.
- oxamido-bridge,
- heterobinuclear complex,
- copper(Ⅱ)-iron(Ⅱ),
- copper(Ⅱ)zinc(Ⅱ),
- magnetism
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