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Citation: LI Bao-Guo, BIAN Zhan-Xi, CAO Li-Zhi, ZHAO Wei. Synthesis and Properties of Ferrocenyl-1,1'-dialkylferrocenylmethanols[J]. Chinese Journal of Applied Chemistry, ;2001, 18(11): 877-880. shu

Synthesis and Properties of Ferrocenyl-1,1'-dialkylferrocenylmethanols

1.
Department of Chemistry, Inner Mongolia University, Huhehaote 010021

Received Date: 28 February 2001
Available Online: 12 July 2001
Fund Project: 内蒙古自治区自然科学基金资助项目(20001301) (20001301)

Ten ferrocenyl-1,1'-dialkylferrocenylmethanols were prepared by reduction of corresponding ferrocenoyl-1,1'-dialkylferrocens with LiAlH₄. The hydroxyl group containing compounds with ethyl groups in 1 and 1' positions of two ferrocenyls are very sensitive to acid, forming stable ferrocenyl-1,1'-dialkylferrocenylmethyl carbocations in CH₂Cl₂ in the presence of BF₃. The cabocations thus obtained in reaction with CH₃CH₂NH₂ gave the corresponding ethylamino compounds. All of the compounds synthesized were characterized by IR and ¹H NMR spectrometric mesurements.
- ferrocenyl dialkylferrocenylmethanol,
- ferrocenoyl dialkylferrocene,
- ferrocenyl diethyl-ferrocenylmethyl carbocation,
- synthesis
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