Citation:
LIU Jin, LI Zhen. Total Synthesis of Sweet Potato Weevil Cylas Formicarius Fabricius Sex Pheromone (Z)-3-Dodecen-1-yl(E)-2-butenoate[J]. Chinese Journal of Applied Chemistry,
;2001, 18(12): 998-1000.
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(Z)-3-dodecen-1-yl(E)-2-butenoate was synthesized starting from acetylene. The key feature of this approach is use of ethylene diamine in the reaction of acetylene and sodium amide for synthesizing 1-decyne. This reaction allowed a convenient preparation of terminal alkyne with a long chain from cheap and common chemicals. The title sex pheromone synthesized showed highly attractant activity in the field to cylas formicarius fabricius.
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