Citation:
LIU Yang, LIU Hong-Tao, XIA Xi. Electrochemical Behavior of Vanadium Compounds at Carbon Paste Electrode(CPE)[J]. Chinese Journal of Applied Chemistry,
;2001, 18(12): 987-990.
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The electrochemical behavior of V2O3, V2O5 and NH4VO3 at carbon paste electrode(CPE) in H2SO4 solution were investigated by cyclic voltammetry. The results showed that for vanadium(Ⅲ) compound there appeared two reduction peaks but three oxidation peaks in cyclic voltammograms in different H2SO4 concentration solutions, while for two vanadium(Ⅴ) compounds there were four reduction peaks and four oxidation peaks, quite close to each other. The corresponding redox peaks were reasonably analyzed and the reaction mechanism has been discussed briefly.
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Keywords:
- carbon paste electrode,
- cyclic voltammetry,
- redox,
- reaction mechanism
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