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Citation: SU Yu-Zhi, WANG Zheng-Hui, HUANG Song-Ling, ZHANG Yong-Hua, GONG Ke-Cheng. The Structure and Properties of Poly(2,2'-diaminophenyloxydisulfide)[J]. Chinese Journal of Applied Chemistry, ;2001, 18(12): 948-952. shu

The Structure and Properties of Poly(2,2'-diaminophenyloxydisulfide)

1.
a Department of Chemistry, Guangzhou University, Guangzhou 510405;
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b Laboratory of Polymer Structure & Modification, South China University of Technology, Guangzhou

Received Date: 29 March 2001
Available Online: 10 September 2001
Fund Project: 国家自然科学基金资助课题(59836232) (59836232)

Poly(2,2'-diaminophenyloxydisulfide)(PDAPO) has been prepared by consecutive cyclic voltammetry. The polymer is characterized by FT-IR, FT-Raman spectra, X-ray photoelectron spectroscopy(XPS), and elemental analysis. In comparison of the shape and response of the cyclic voltammogram of the polymer with those of its monomer, it become clear that the redox process of the PDAPO is more reversible than the other oganodisulfide polymers owing to the intramolecular electrocatalytic effect of polyaniline and the strong electron-donating effect of -O-S-S-O- bonds in the polymer structure. The electric conductivity, thermal stability and surface morphology also have been investigated. The results show that PDAPO is a highly electroactive and electroconducting polymer which could be used as a novel positive material for lithium battery or lithium secondary battery.
- poly(diaminophenyloxydisulfide),
- structure,
- property,
- conducting polymer,
- electroactivity
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