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Citation: JIN Xiang-Jun, LI Xiao-Ping, MEN Yong, XIAO De-Hai, LI Jing, YANG Xiang-Guang, WU Yue. Synthesis of Mesoporous Molecular Sieve M-HMS for Catalytic Hydroxylation of Phenol[J]. Chinese Journal of Applied Chemistry, ;2002, 19(3): 247-250. shu

Synthesis of Mesoporous Molecular Sieve M-HMS for Catalytic Hydroxylation of Phenol

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a Baicheng Teachers' College, Baichen;
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b Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Corresponding author: YANG Xiang-Guang,
Received Date: 23 June 2001
Available Online: 29 November 2001
Fund Project: 国家自然科学基金(29973041)资助项目 (29973041)

The mesoporous molecular sieves M-HMS(M=Fe,Cu,Co,V) were synthesized by using dodecylamine as template and characterized by XRD, IR, ESR. The results revealed the incorporation of the transition metal ions in the HMS framework. It was found that catalytic activity of M HMS in hydroxylation of phenol by H₂O₂ was obviously higher than that of the supported catalysts, M/SiO₂(M=Fe,Cu,Co,V) at the same reaction conditions. The active site of the M-HMS appeared the transition metal ion incorporated in HMS framework.
- HMS mesoporous molecular sieve,
- phenol hydroxylation,
- dipenol
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