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Citation: GUO Jin-Tang, WANG Xin-Ying, YANG Jun-Hong, XU Yong-Shen, SUN Jing-Wu. Synthesis and Characterization of Glycidol ether-CO₂ Copolymers[J]. Chinese Journal of Applied Chemistry, ;2002, 19(3): 234-238. shu

Synthesis and Characterization of Glycidol ether-CO₂ Copolymers

GUO Jin-Tang ^a,b,, ,
WANG Xin-Ying ^a,b ,
YANG Jun-Hong ^c ,
XU Yong-Shen ^a,b ,
SUN Jing-Wu ^a,b

1.
a State Key Laboratory of C1 Chemical Technology, Tianjin University, Tianjin 300072;
2.
b School of Chemical Engineering, Tianjin University, Tianjin 300072;
3.
c School of Electric Automation & Energy Engineering, Tianjin University, Tianjin 300072

Corresponding author: GUO Jin-Tang,
Received Date: 19 June 2001
Available Online: 9 October 2001

Some glycidol ether monomer(GE) were prepared by reacting epichlorohydrin(ECH) with phenol and/or alcohol; T-allyl glycidol ether, U-chloroethyl glycidol ether, benzene glycidol ether, m-tolyl glycidol ether, benzyl glycidol ether. And aliphatic polycarbonates were synthesized by copolymerization of CO₂ with GE catalyzed by coordination catalyst composed of Y phosphonate and triisobutylaluminum[Y(P₂0₄)₃-Al(i-Bu)₃]. The copolymers were characterized by IR, ¹H NMR, ¹³C NMR, WXRD, TG and dynamic mechanical analysis. The results showed that Y(P₂0₄)₃-Al(i-Bu)₃₂ with GE and the preferred amount of catalyst was 2.7×10^-2~5.0×10^-2mol/L. The thermal analysis revealed the thermal resistance of the copolymers prepared by CO₂ and GE with benzene ring was higher than that of the copolymer prepared by CO₂ and ECH. The glass transition temperature of the m-tolyl glycidol ether-CO₂ copolymer was 26.6℃.
- CO₂,
- glycidol ether,
- copolymerization,
- thermal property
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Synthesis and Characterization of Glycidol ether-CO₂ Copolymers