Citation:
HUANG Zhi-Hong, XIE Zhi-Ming, LI Zhuo-Mei. Studies on Crosslinking of Acrylate Copolymer Soap-free Hydrosol with Zirconium Chelate Ⅱ The Crosslinking Reaction of Acrylate Tercopolymeric Soap-free Hydrosol with Zirconium Chelate[J]. Chinese Journal of Applied Chemistry,
;2002, 19(3): 224-229.
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The effects of the amount of crosslinking agent zirconium chelate ZrE on the properties of acrylate hydrosol and hydrosol film at different temperatures were discussed. In copolymer hydrosol, ZrE could interact with copolymer and change the hydrosol viscosity, surface tension and stability, and also improve the water resistance of the hydrosol film. IR, 1H NMR, DSC, TGA and UV analysis were used to study the reaction mechanism.
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