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Citation: MA Xue Bing, FU Xiang-Kai, LI Long-Qin, CHEN Jing-Rong. Synthesis of N,N-Bis(diphenylphosphinomethyl) piperazine and Its Palladium Complexes and Catalytic Carbonylation of Benzyl Chloride[J]. Chinese Journal of Applied Chemistry, ;2002, 19(4): 359-363. shu

Synthesis of N,N-Bis(diphenylphosphinomethyl) piperazine and Its Palladium Complexes and Catalytic Carbonylation of Benzyl Chloride

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a College of Chemistry and Chemical Engineering, Southwest China Normal University Chongqing 400715
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Corresponding author: FU Xiang-Kai,
Received Date: 28 August 2001
Available Online: 31 December 2001
Fund Project: 重庆市科委应用基础资助项目(2000-6262) (2000-6262)

A novel amphiphilic phosphine ligand N,N-bis(diphenylphosphinomethyl)piperazine was synthesized by reaction of piperazine with[Ph₂P(CH₂OH)₂]+Cl^- in the medium with pH ranged in 9~10 at 65~70℃ for 2.5 h in 97% yield, and characterized by elemental analysis, NMR, MS, IR and UV. Its palladium complexes with different molar ratio of Ph₂P to Pd were prepared in n-butanol. XPS data revealed that the coordination bonds were formed between phosphorous and palladium atoms in the palladium complexes 1a, 1b. High catalytic activities of the complexes 1a, 1b were observed in carbonylation of benzyl chloride with CO. The catalyst could be reused repeatedly in five times.
- N,N-bis(diphenylphosphinomethyl)piperazine,
- amphiphilic phosphine,
- palladium complex,
- carbonylation
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