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Citation: FENG Ya-Fei, SONG Yu-Min, GAO Jin-Zhang, KANG Jing-Wan, YANG Wu. Synthesis, Characterization and Fluorescence Properties of Lanthanide Complexes of N,N',N"-Tri(3,5-dinitro benzenesulfonyl)-1,4,7-triazacyclononane[J]. Chinese Journal of Applied Chemistry, ;2002, 19(4): 334-337. shu

Synthesis, Characterization and Fluorescence Properties of Lanthanide Complexes of N,N',N"-Tri(3,5-dinitro benzenesulfonyl)-1,4,7-triazacyclononane

1.
a Department of Chemistry, Lanzhou Teacher's College, Lanzhou;
2.
b College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Corresponding author: GAO Jin-Zhang,
Received Date: 8 August 2001
Available Online: 14 December 2001
Fund Project: 国家自然科学基金资助项目(29875018) (29875018)

Six complexes of N,N',N"-tri(3,5-dinitro benzenesulfonyl)-1,4,7-triazacyclononane(TDNBS-Tacn) with rare earth(La,Ce,Pr,Nd,Sm and Eu) were synthesized and their compositions were characterized by elemental analysis, ¹H NMR, IR spectra and UV-Vis spectrum. Under the optimal conditions, the fluorescence spectra of complexes have a maximum excitation wavelength at 256 nm and maximum emission wavelength at 408 nm. The results indicate that the complexes have excellent luminescence properties.
- rare earth complex,
- N,N',N"-tri(dinitro benzenesulfonyl)-triazacyclononane,
- synthesis,
- fluorescence property
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