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Citation: GUO Kai, ZHANG Shu-Yuan, HE Ke-Ke, ZHENG Shi-Jun, ZHANG Teng, YAN Tao, LI Zi-Fa. Synthesis and Characterization of Diaminodibenzo-14-crown-4[J]. Chinese Journal of Applied Chemistry, ;2002, 19(4): 329-333. shu

Synthesis and Characterization of Diaminodibenzo-14-crown-4

GUO Kai ^a ,
ZHANG Shu-Yuan ^b ,
HE Ke-Ke ^a ,
ZHENG Shi-Jun ^a ,
ZHANG Teng ^a ,
YAN Tao ^a ,
LI Zi-Fa ^a,,

1.
a College of Material Engineering, Zhengzhou University, Zhengzhou 450052;
2.
b Department of Chemistry, Zhengzhou University, Zhengzhou 450052

Corresponding author: LI Zi-Fa,
Received Date: 16 August 2001
Available Online: 12 November 2001
Fund Project: 国家自然科学基金(29974026) (29974026)

Cis-and trans dinitrodibenzo-14-crown-4 were synthesized via nitration of dibenzo-14-crown-4(DB14C4D) synthesized by a modified Pedersen method. Cis-and trans-diaminodibenzo-14-crown-4 (cis-DAmDB14C4 and trans-DAmDB14C4) were obtained by reduction of NO₂ group using Pd/C catalyst. All the compounds were characterized by NMR, IR and elemental analysis. The stereo structures of the cis-and trans-diaminodibenzo-14-crown-4 in DMSO have been investigated by ¹H NMR, ¹³C NMR and computer simulation.
- dinitrodibenzo-crown ether,
- diaminodibenzo-crown ether,
- synthesis
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Synthesis and Characterization of Diaminodibenzo-14-crown-4

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com