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Citation: ZHANG Cun-Zhong, LEI Jing-Lei, CAI Sheng-Min, YANG Mai-Zhi, TIAN He. On the Chemical Reduction and Electro- reduction Behavior of Perfluorodecalin[J]. Chinese Journal of Applied Chemistry, ;2002, 19(5): 506-508. shu

On the Chemical Reduction and Electro- reduction Behavior of Perfluorodecalin

1.
a College of Chemistry & Molecular Engineering, Peking University, Beijing 100871;
2.
b Institute of Fine Chemicals, East China University of Science & Technology, Shanghai

Corresponding author: CAI Sheng-Min,
Received Date: 26 December 2001
Available Online: 21 March 2002
Fund Project: 国家自然科学基金(29877003) (29877003)

The chemical reduction and electro-reduction behavior of perfluorodecalin have been investigated under the illumination of UV light. The IR spectra of the resulting products showed that the same functional group, acyl fluoride, could be formed in both reduction processes. The results of ¹⁹F NMR and UV-vis spectra revealed that there were other different functional groups formed in the two reduction processes. In the electro chemical reduction, conjunctive double bonds could be formed in the same and different carbon ring. In the chemical reduction, using Zn and Mg as reducing agents, aromatic structure was formed in the products.
- perfluorodecalin,
- reduction,
- electro-reduction
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