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Citation: GUO Ying-Chen. Synthesis of N,N'-Bis(o-hydroxy-p-methoxybezophenone)-ethylenediamine Complexes with Copper(Ⅱ)、Nickel(Ⅱ) and Cobalt(Ⅱ)[J]. Chinese Journal of Applied Chemistry, ;2002, 19(5): 503-505. shu

Synthesis of N,N'-Bis(o-hydroxy-p-methoxybezophenone)-ethylenediamine Complexes with Copper(Ⅱ)、Nickel(Ⅱ) and Cobalt(Ⅱ)

GUO Ying-Chen ^,

1.
Department of Chemistry, Nanyang Teacher's College, Nanyang 473061

Corresponding author: GUO Ying-Chen,
Received Date: 8 August 2001
Available Online: 6 November 2001

The N,N'-bis(o-hydroxy-p-methoxybezophenone)-ethylenediamine complexes with copper(Ⅱ) 、nickel(Ⅱ) and cobalt(Ⅱ)[MC₃₀H₂₆N₂O₄] were synthesized by solid-liquid phase reaction. The complexes were characterized by elemental analysis, XRD, UV, IR and ¹H NMR. The crystal structure of the complexes belongs to triclinic system with the cell parameters: a=1.297 1 nm, b=1.621 0 nm, c=2.047 0 nm, T=85.40°,U=88.80°, V=99.00° for[CuC₃₀H₂₆N₂O₄·0.5H₂O]; a=1.300 2 nm, b=1.882 6 nm, c=2.127 4 nm, T=86.47°,U=89.23°, V=99.11° for[NiC₃₀H₂₆N₂O₄]; a=1.286 5 nm, b=1.596 1 nm, c=2.056 9 nm, T=87.95°, U=93.17°, V=98.21° for[CoC₃₀H₂₆N₂O₄], respectively. The N and O atoms in the complexes appeared coordinated directly to the metal ions. A quadridentate chelate may be formed.
- N,N'-bis(o-hydroxy-p-methoxybezophenone)-ethylenediamine,
- complex,
- Cu(Ⅱ),
- Ni(Ⅱ),
- Co(Ⅱ),
- synthesis
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