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Citation: SONG Yi-Bing, YU Lin, SUN Chang-Yong, YE Fei, FANG Yi-Wen, LIN Wei-Ming. Catalytic Oxidation of Glucose over the catalyst Pd-Co/C[J]. Chinese Journal of Applied Chemistry, ;2002, 19(10): 976-980. shu

Catalytic Oxidation of Glucose over the catalyst Pd-Co/C

SONG Yi-Bing ^a,b ,
YU Lin ^b,, ,
SUN Chang-Yong ^b ,
YE Fei ^b ,
FANG Yi-Wen ^b ,
LIN Wei-Ming ^a

1.
a Department of Chemical Engineering, South China University of Technology, Guangzhou;
2.
b Department of Chemistry, Shantou University, Shantou 515063

Corresponding author: YU Lin,
Received Date: 1 March 2002
Available Online: 10 May 2002
Fund Project: 广东省教育厅自然科学基金项目(200065) (200065)

The activities of Pd/C、Pd-Co/C catalysts have been evaluated in a self-made batch reactor and characterized by BET、XRD and XPS techniques. The results show that Pd-Co/C catalyst exhibits the glucose conversion activity of 92%, with 94% selectivity to glucose acid after reaction for 3 h. The BET measurement reveals the increased distribution of the larger pore size of Pd-Co/C catalyst in comparison with that of Pd/C as a result of the addition of Co and the sequent catalyst calcination. The XPS characterization indicates higher concentration and dispersion of palladium species on the surface of Pd-Co/C catalysts compared with Pd/C catalyst. This suggests the easy reduction of the Pd species located on the surface of Pd-Co/C catalysts. The Pd-Co/C catalyst exhibits better catalytic performance for oxidation of glucose than Pd/C catalyst.
- glucose,
- Pd-Co/C catalyst,
- catalytic oxidation
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