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Citation: YANG Bing-Qin, GUO Yuan, WANG Yun-Xia. Synthesis of (4,4'-Diaminobiphenylene-2,2') disulfonic Acid[J]. Chinese Journal of Applied Chemistry, ;2002, 19(11): 1118-1119. shu

Synthesis of (4,4'-Diaminobiphenylene-2,2') disulfonic Acid

1.
Department of Chemistry, Northwest University, Xi'an 710069

Corresponding author: YANG Bing-Qin,
Received Date: 25 December 2001
Available Online: 24 July 2002
Fund Project: 陕西省自然科学基金资助项目(FF01202) (FF01202)

Sodium m-nitrobenzene sulfonate was reduced by formal solution to give disulfo azoxybenzene. The latter was reduced by an alkali solution of glucose at 94~96℃ for 5 hours to give hydrazobenzene disulfonic sodium (2). The title compound was obtained by rearrangement of (2) by hydrochloric acid in yield of 81.5%. The method has the advantages of cheapness and high yield.
- nitrobenzenesulfonate,
- diaminobiphenylene disulfonic acid,
- glucose,
- formaldehyde
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