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Citation: TAO Ruo-Jie, ZANG Shuang-Quan, ZHAO Ge, YU Zhao-Wen, NIU Jing-Yang, ZHOU Xu-Ya. Synthesis and Crystal Structure of Binuclear Heterometal Complex, CuZnTS·CH₃OH[J]. Chinese Journal of Applied Chemistry, ;2002, 19(11): 1059-1063. shu

Synthesis and Crystal Structure of Binuclear Heterometal Complex, CuZnTS·CH₃OH

1.
College of Chemistry and Chemical Engineering, He'nan University, Kaifeng 475001

Corresponding author: TAO Ruo-Jie,
Received Date: 12 April 2001
Available Online: 8 July 2001
Fund Project: 河南省杰出青年基金(0040301800) (0040301800)河南省科委基金(211021300)资助项目 (211021300)

The complex CuZnTS·CH₃OH, where TS denotes the binuclear ligand derived from the Schiff base N,N'-bis(3-carboxylsalicyl aldehyde)trimethylenediamine, was synthesized and its crystal structure was determined by the single-crystal X-ray diffraction method at room temperature. The complex crystallizes in triclinic system with space group P1. The lattice parameters are a=0.94403(19) nm, b=1.1591(2) nm, c=0.91322(18) nm, and T=91.09(3)°, U=97.06(3)°, V=75.06(3)°, Z=2 with R1=0.0499, wR2=0.0318. The structure is consisted of heterobinuclear units, where the copper atom is fivefold coordinated by two nitrogens, two phenolic oxygens, and one oxygen of a methanol molecule in a distorted square pyramid, and the zinc atom is also in a distorted square pyramid manner, coordinated by two phenolic oxygen atoms, two equatorial carboxyl oxygen atoms and one oxygen of the adjacent molecular. The cyclic voltametric behavior of the complex is briefly examined.
- heterometal binuclear complex,
- crystal structure,
- electrochemical property
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Synthesis and Crystal Structure of Binuclear Heterometal Complex, CuZnTS·CH3OH

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Synthesis and Crystal Structure of Binuclear Heterometal Complex, CuZnTS·CH₃OH