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Citation: TAO Ruo-Jie, LOU Ben-Yong, ZANG Shuang-Quan, ZHOU Xu-Ya, WANG Qing-Lun, LIAO Dai-Zheng. Electrochemical and Magnetic Property of Trinuclear Complexes Bridged by Oxamide[J]. Chinese Journal of Applied Chemistry, ;2002, 19(12): 1158-1161. shu

Electrochemical and Magnetic Property of Trinuclear Complexes Bridged by Oxamide

1.
a School of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001;
2.
b Department of Chemistry, Nankai University, Tianjin

Corresponding author: TAO Ruo-Jie,
Received Date: 17 April 2002
Available Online: 24 July 2002
Fund Project: 河南省科技厅自然科学基金资助项目(211021300) (211021300)

Two novel heterotrinuclear complexes [Cu(oxca)]₂M(H₂O)₂ where oxca denotes N-(2-carboxy phenyl)-N'-(3-aminopropyl) oxamide and M=Co²⁺, Ni²⁺ have been synthesized. The results of IR, elemental analysis, conductivity measurements, electronic spectra and thermogravimetry analysis indicate that the complexes have an extended oxamido-bridged structure. The variable-temperature magnetic susceptibility measurements of {[Cu(oxca)]₂Co(H₂O)₂} over the range 4~300 K gave the exchange integral J=-28.09 cm^-1.
- heterotrinuclear oxamide bridged complex,
- cyclic votammetry,
- antiferromagnetic interaction
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