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Citation: HU Yu-Ling, FENG Yu-Qi, DA Shi-Lu. Ion-exchange and Ligand-exchange Properties of Zirconia and Zirconia-ceria Stationary Phases[J]. Chinese Journal of Applied Chemistry, ;2002, 19(12): 1123-1127. shu

Ion-exchange and Ligand-exchange Properties of Zirconia and Zirconia-ceria Stationary Phases

1.
a School of Chemistry & Chemical Engineering, Sun Yat-sen University, Guangzhou;
2.
b Department of Chemistry, Wuhan University, Wuhan 430072

Received Date: 5 April 2002
Available Online: 5 August 2002
Fund Project: 国家自然科学基金资助项目(29875020) (29875020)

Zirconia and zirconia-ceria microspheres were synthesized as stationary phases for HPLC by a sol-gel process. The chromatographic behavior of inorganic anions and benzoic acid derivatives was systematically investigated. Zirconia and zirconia-ceria exhibit anion-exchange property only in the pH value below their zero change points. The elution order of five inorganic anions are I^-, Br^-, NO₃^-, NO₂^-, NO₃^-. Benzoic acid derivatives showed a more retention value on zirconia and zirconia-ceria mainly by ligand-exchange interaction, and the retention values were attenuated by the addition of a competing Lewis bases to the mobile phase. Moderate retention of benzoic acid derivatives on zirconia and zirconia-ceria can be obtained by using acetate buffer as a mobile phase.
- zirconia,
- zirconia-ceria,
- ion-exchange,
- ligand exchange,
- HPLC
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