Citation:
LI Ming-Xiu, GAO Yuan-Zhe, WANG Ji-Ye. Effect of Erbium Additive on the Catalytic Property of Mo-Bi-O[J]. Chinese Journal of Applied Chemistry,
;2003, 20(3): 242-245.
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Erbium oxide was added to Bi2O3-MoO3 mixed oxides catalyst(Mo-Bi-O) via coprecipitation. Reaction temperature, concentration of isobutene in air and ratio of Er2O3 in the Mo-Bi-O catalysts were studied in a fixed bed reactor. The results showed that conversion of isobutene and selectivity for methacrolein was improved when erbium oxide was added in the catalyst. The maximum yield of methacrolein was obtained when proportion of erbium reached 15%. XRD patterns of the catalyst samples revealed that the main component of the Mo-Bi-O catalyst with added erbium is Er2Mo3O12.
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