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Citation: ZHOU Xiao-Shuang, LIU Jing, XU Jie, TAN Zhong-Yin. Synthesis of Glutaraldehyde by Oxidation of Cyclopentene with Peroxyformic Acid[J]. Chinese Journal of Applied Chemistry, ;2003, 20(6): 600-602. shu

Synthesis of Glutaraldehyde by Oxidation of Cyclopentene with Peroxyformic Acid

1.
a Dalian Institute of Chemical Physics, Dalian 116023;
2.
b Department of Chemistry, Liaoning Normal University, Dalian

Corresponding author: XU Jie,
Received Date: 26 December 2002
Available Online: 7 April 2004
Fund Project: 中国科学院领域前沿(2002年创新基金)资助项目 (2002年创新基金)

A preparation method of glutaraldehyde by one-step oxidation of cyclopentene with peroxyformic acid is reported.The preparation is carried out in a mild reaction condition,time saving and without catalyst.The product is identified by MS and IR measurements.The results showed that the highest yield of glutaraldehyde 56.7% is obtained at optimum molar ratio of n(hydrogen peroxide):n(cyclopentene):n(formic acid)=1:3:3,reaction temperature 35℃ and reaction time 1 h.
- glutaraldehyde,
- cyclopentene,
- formic acid
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