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Citation: LI Ren-Yu, BEI Feng-Li, YANG Xu-Jie, XU Xing-You, LU Lu-De, WANG Xin. Solid Phase Synthesis, Characterization and Crystal Structure of N-(4-Hydroxyphenylmethylene)-1-Naphthylamine[J]. Chinese Journal of Applied Chemistry, ;2003, 20(9): 911-913. shu

Solid Phase Synthesis, Characterization and Crystal Structure of N-(4-Hydroxyphenylmethylene)-1-Naphthylamine

LI Ren-Yu ^a,b ,
BEI Feng-Li ^a ,
YANG Xu-Jie ^a ,
XU Xing-You ^a ,
LU Lu-De ^a,, ,
WANG Xin ^a

1.
a Materials Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094;
2.
b Lianyungang Teaching College, Lianyungang

Corresponding author: LU Lu-De,
Received Date: 29 December 2002
Available Online: 13 May 2003
Fund Project: 江苏省自然科学基金资助项目(BK2002100) (BK2002100)

N-(4-Hydroxyphenylmethylene)-1-naphthylamine was synthesized by the solid phase reaction of 1-naphthylamine and 4-hydroxybenzaldehyde at room temperature. The reaction was completed in 15 min in yield of 95%. The product was characterized by elemental analysis, IR, X-ray powder diffractometry and ¹H NMR. The crystal as determined by X-ray single crystal diffractometry belongs to monoclinic system with space group P2₁/c, a=1.004 9(2), b=1.047 3(2), c=1.200 2(2) nm, β=92.60(3)°, V=1.261 8(4) nm³, D_c=1.302 g/cm³, Z=4, F(000)=528, μ=0.081 mm^-1, R=0.0375, wR=0.106 2, S=1.024.
- N-(hydroxyphenylmethylene) naphthylamine,
- Schiff base,
- solid phase reaction,
- crystal structure
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